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Life of Soot: Diesel Pollution, Emissions, and Health Effects Page 1 of5
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# UNION OF CONCERNED SCIENTISTS
Citiuns and Scientists for Environmental Solutions
www.ucsusa.org
Clean Vehicles
B Ma U this to a frie nd
backgrounder
Diesel Pollution Primer
soot formation, emissions, dispersal, and health effects
At some point or another, we've all
gotten caught behind an l8-wheeler,
a garbage truck, a tractor, or a
bulldozer and seen, smelled, and
even felt the clouds of soot coming
from their tailpipes.
But how and why does diesel fuel
produce this haze of soot, or
particulate . matter (PM), and how
does it affect the bodies of those who
~"'- ~ breathe it in? In this backgrounder
we take a look at the lifecycle of soot and. explore its
implications.for your family's health.
The Birth of Soot
Soot, or particulate matter (PM), begins its life in the belly of both gasoline and
diesel-powered engines. These engines create chemical and organic compounds
from the combustion of hydrocarbon-based fuels (fossil fuels). These
compounds then cluster together in particle form to create soot, which is released
into the air as exhaust. Soot may also come to life as the indirect byproduct of
nitrogen oxides (NOx) and sulfur dioxides (SOx) reacting in the
atmosphere. Soot) s composition often includes hundreds of different chemical
elements, including sulfates, ammonipm, nitrates, elemental carbon, condensed
organic compounds, and even carcinogenic compounds and heavy metals such as
arsenic, selenium, cadmium and zinc.l
One of reasons conventional diesel engines
release more soot than their conventional -'
gasoline counterparts has to do with the '" ~iLATEO Ll~KS
way fuel is injected and ignited: on gas in, clean vehicles
engines, fuel is injected during the intake R~.Q1't: Sick Q(S.~19J
stroke and ignited with a spark; on diesels,
fuel is injected during the compression ,Analys1~-= Ilean~uty_
stroke, and the fuel ignites spontaneously Dies_el
from the pressure. As a result, gas engines CA_,Diesel Ri_s_k_Reduct~JJ
have two emissions advantages: The :PblD
ignition process is more carefully Diesel_E.ugines & P.l.tbJ,i~
controlled and the air and fuel are more B~.;llth
thoroughly mixed before ignition occurs,
thereby reducing the amount of unburned o ff.site
fuel.
In a conventional diesel, fuel is injected CleanS~_hoolBus.org
late in the cycle and the air is not as well Campaign
mixed as in a gasoline engine. As a result
of this less homogeneously mixed fuel and
air, there are fuel-dense pockets in the combustion chamber. The consequence is
that diesel engine exhaust contains incompletely burned fuel (soot) known as
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Life of Soot: Diesel Pollution, Emissions, and Health Effects Page 2 of5
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particulate matter. ~
But it's not "engine-out" pollution that really matters-if's what comes out of
the tailpipe. Gasoline engines have gotten a lot cleaner over time through the use
of add-on pollution controls, . like catalytic converters. The environmental
Protection Agency (EPA) has passed increasingly stricter standards for gasoline
engines, and as a result, catalytic converters are now standard on every new gas
car.
The real reason diesels pollute more
soot is that EP A has not forced them to
meet the stricter standards facing
gasoline engines. The soot standard for
diesel cars under EP A's Tier 1
regulation is at least ten times the
average emission from a gasoline car.
But under the new Tier 2 regulations,
which will phase in between 2004 and
2009!1 diesels will fmally have to meet
the same strict standard as gasoline cars.
A diesel engine particulate filter Diesel cleanup technology has come a
system long way. From diesel particulate traps
to oxidation catalysts, there are now
various methods of catching or converting much of diesel pollution before it
escapes the tailpipe. Starting in 2009, all diesel light trucks and cars will have to
meet the same tailpipe standards as gasoline vehicles.
But new engine standards alone are not enough to protect the public from diesel
pollution. New standards for diesel engines will be slowly phased in over the
next 10 years. Plus, the durability of diesel engines means that older, high-
polluting vehicles can continue to operate for decades. Diesel soot emissions are
furthered by the fuel itself, as today's conventional diesel fuel contains
significantly more sulfur than does gasoline~J
Soot's exact composition is difficult to characterize because different engine
technologies and conditions produce different types of soot. Indeed, the smoke
clouds coming from diesel engines can even have different colors. For example,
blue smoke (mainly oil and unbumt fuel) can indicate a poorly serviced and/or
tuned engine; black smoke (soot, oil and unburnt fuel) can indicate a mechanical
fault with the engine; and white smoke (water droplets and unburnt fuel) is
produced when the engine is started from cold and may disappear when the
en~ine warms up.4
The soot in. your neighborhood may be different than the soot in someone else's
hometown, but no matter the source and type, soot can present a grave health
threat.
oot's Journey Across the Land
s previously mentioned, soot particles either come
irectly from the tailpipe, or can be formed when tailpipe
missions of NO x and SOx react with atmospheric agents.
nee formed, soot comes in many sizes, though all just a
fraction of the width of a human hair, from coarse PM (less than 10 microns in
'diameter) to fine PM (less than 2.5 microns) to ultrafine PM (less than 0_1
microns)_ Most soot is in the fine and ultrafine categories, with ultrafine particles
making up 80-95%, of soot. Ultrafine particles are the most dangerous!I however,
as they are small enough to penetrate the cells of the lungs. Soot particles can
have an environmental lifetime of one to three weeks, and they can travel long
distances, journeying to communities in far regions. Soot particles have even
been found at the South Pole, where no major emission source exists for
thousands of miles. 5
But in general, soot tends to fall out of the atmosphere close to the source of the
pollution. The further you are away from diesel exhaust sources, the better for
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your health, and vice-versa. In California, the home of the nation's largest fleet
of diesel vehicles, roughly 80 percent of the state's diesel pollution sources are
found in 5 of the 15 air basins. Showing that the effects of diesel soot are, mostly
close to the source, about 87% of California's over $21.5 billion yearly diesel
exhaust-related health care costs come from the same 5 air basins.Q
Estimated Premature Deaths by Diesel Exposure by CA Air Basin
?_Nonheast Plateau (3)>
(~}::\..;.:: ~sacramonto V;JIlloy (172)
North Coaat (9) ~ .'. . Mo nta. Co t'.. (7J
\ , ,~i ~"'a~ u en un ,
uko COllnty (<1)'j~;~~.~, Cd. LaM 1"ahoo (1)
,\: .~" .~. nJoaQulnValley(2601
.. " "<, ."''';- "',~~ ~ ~~~~
Sa... Fr.anc:,"o ~ ,) , f*1l.~ 9'17 ~
I!r~ (6GO) " ':::~ ~ ' _
~"'~"'-1,~ ~ ii}~~,
k~P4
NorIb Central .. ':>!i'!:~ .1t~
CoaS:;;~~7;.i~,,~!;~~{Ii,MO~VO Desert (23)
_-:c,;-....;.<:<<__.;: ..~~~,..._... .":;:. , ._
South' Coast (1~415) J,':' -;~;.' -~.~/:--'\~\\<.:'~~.~'.':\.~
San Diogo (244) ~ ~ Salton Sea (31)
NOTE: Premature deaths are a result of exposure to diesel particulate matter, .
both direct from the tailpipe and from the conversion of NOx emissions to
particulates in the atmosphere. Estimates for indirect particulate exposure for
each air basin are based on a conversion of NOx emissions to particulates.
SOURCE: Image courtesy of CARB.
Soot's Trip Through Y oor Body
As soot travels through the air in your community, you breathe it in, and so it
starts the next phase of its journey: a trip through your body's respiratory system.
Large soot particles (> 10 microns) deposit in your nose, throat, and lungs,
causing coughing and sore throat, and are ejected from your body through
sneezing, coughing, and nose blowing. Coarse particles (10 microns) are inhaled
into your windpipe and settle there, causing irritation and more coughing. Fine
and ultrafine particles (less than 2.5 microns) are the most successful in invading
your body, small enough to travel all the way down deep into your lungs.
, IDi~~~IS~~t-~h;;ti~~.-- I Once there, these soot particles can
1 irritate and mutate the most sensitive
tissues in your lungs: your alveoli. These
air sacs line your lung's alveolar ducts
and are the primary gas exchange units
of the lungs. Surrounded by networks of
'blood capillaries, alveoli exchange
oxygen and carbon dioxide from the air
you breathe in with blood in your
capillaries, thus allowing your
circulatory system to carry oxygen to the
rest of your body. Soot particles,
however, make this task more difficult as
they cause inflammation and scarring of
these alveoli. 7. Scar tissue builds up and
slows oxygen flow to your capillaries,
Click the image above to see how soot straining your heart because it must work
travels through the body in this harder to compensate for oxygen loss.
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Life of Soot: Diesel Pollution, Emissions, and Health Effects Page 4 of5
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animation (courtesy of the Long Beach Soot also finds other ways to harm your
Press Telegram's Toxic Air Se.rie~) body, including causing chronic
bronchitis and asthma. These conditions
occur when the linings of your lung's bronchioles (air passageways) become
irritated and swollen, in turn causing your lungs to create mucus to soothe the
irritation. These conditions prevent your bronchioles from moving oxygen to the
rest of your body. Symptoms can range from coughing and shortness of breath
to severe and fatal attacks of oxygen loss.. In addition, soot particles also reduce
your respiratory system's ability to fight infections and remove other foreign
particles.
Soot particles can also act as carriers of carcinogenic compounds into your body..
Compounds in soot such as polycyclic arOmatic hydrocarbons (P AHs) are
carcinogenic, and diesel soot itself is classified by many government agencies as
either a probable or known cancer-causing agent. For example, the California
Air Resources Board has concluded that diesel soot is responsible for 70 percent
of the state's risk of cancer from airborne toxies.
Lastly, diesel pollution can be deadly, causing premature mortality through
cancer or heart and respiratory illnesses. In the population as a whole, studies
have shown a 26% increase in mortality in people living in soot-polluted cities.
Soot's Harms Vulnerable Populations Most
Although all human beings are susceptible to soot's journey through their body,
individuals with preexisting respiratory conditions, children, and the elderly are
the most vulnerable to soot's lasting and deadly effects. People with heart
disease, emphysema, asthma, and chronic bronchitis suffer from increased
hospital adm~ssions and emergency room visits as a result of exposure to soot.
Children-and their developing ~ungs-may also
suffer more acutely from breathing in diesel
soot. Outdoors more often and breathing in more air
per body weight than adults do, children suffer
disproportionately from asthma and other
respiratory conditions. Asthma is the most common
chronic disease of childhood and a leading cause of
disability among children; today about one in
thirteen children have asthma. Elderly persons also
bear a large burden when coming in contact with
soot. Studies estimate that tens of thousands of
elderly people die prematurely each year from
exposure to ambient levels. of fine PM.8.
A Costly Journey
In the end, soot travels far and wide to affect thousands of communities and
millions of people, including you and your family. It begins in the combustion of
an engine and ends up in the innermost reaches of individuals' lungs. Society
pays a heavy price for soot's journey.. Billions of dollars in health cwe costs, the
loss of work and school days, and-the loss of human lives create an enormous
burden for society to shoulder. This burden is not a necessary one, however, as it
can be lifted from off our backs with the help of stricter air regulations and
cleaner engine technology .
Notes
1) Minnesota Pollution Control Agency: Particulate Matter (TSP and PM-I0) in
, Minnesota..- !Y..ww.ll-~.MjJ1e.mn~!ls/air/eD1l~sions/pmlfl,-b1ml
2) Diesel Technology Forum: New 'Teclmologies: Diesel Filters-..
httD:llwww.dies~lforum..9xg{factsh~eJ/tr~.llLm-1
3) Sierra Club: Health Effects Associated with Diesel Emissions-..
http://wwjy~i~J:n~xl]tb.!-Q.rgLcle~nair/facJsheets/ diesel.~p-
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Life of Soot: Diesel Pollution, Emissions, and Health Effects Page 5 of5
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4) Health & Safety Executive: Diesel Engine Exhaust Emissions .-
h!tp:/lwww .-'lS~~9.Y._Jtkl~\lbns/j ndg186. bim
5) Environmental Health Perspectives: Seeing Through Soot-...
bttn:II~~Djehs.niJLgpv Im~mb~.rs/2001l11 0-8/in~ov aJIQDs. html
6) Union of Concerned Scientists: Sick of Soot, pp. x-xi
7) Long Beach Press Telegram: Toxic Air: How Poor Air Quality Affects the Respiratory
System .... J1ttp:/ /la_W1-~,~stel~nlm!com/projects/tQ~kairI.IDedi~.&l~ic~kJqgg~~wf
. 8) US Environmental Protection Agency: Health and Environmental Effects of Particulate
Matter -- bttp_~!Jwww.~.~ov Ittn/ oa-wgLMJlq!.tIDLp_mhJ~}!lth....btml
Page Last Revised:
http://www..ucsusa.org/clean_ vehicleslbig__rig_ cleanup/l ife-of-soot-diesel-pol lution-emissions-and-hea 1... 5/1/2006
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Big Rig Cleanup i~ex Page 1 of 1
UNION OF CONCERNED SCIENTISTS
Citizens and Scientists for Environmental Solutions
www.ucsusa.org
Clean Vehicles
EJ Ma il1:his 1:0 a 1rie nd
big rig cleanup
"Big rigs" haul our goods. They dig our ditches.
They harvest our crops. They drive our children
to school. But these OD- and off-road vehicles-
trucks, buses, tractors, and combines, just to
name a few-are often forgotten when discussing
the health, energy security, and environmental
impact of transportation in America.
Diesel engines, which power a majority of big
rigs, release a mixture of smog-forming
pollutants, particulate matter (soot) that can
penetrate deep into our lungs, and other toxic
constituents such as arsenic, cadmium, dioxin,
and mercury. Children, because their lungs are
developing, are particularly vulnerable to diesel
exhaust, which has been linked to a host of
severe health problems including asthma, cancer,
and even premature death.
Cleaning up big rigs has been an extremely slow
and difficult task. DeS is working to raise
awareness of the severity and importance of this
issue, as well as creating and preserving the
solutions that will ensure a healthier future for us
and our children. Our cleanup strategy includes:
. advocating strict emission standards for
new highway and off-highway engines
. providing incentives and passing
regulations to clean up existing engines
. replacing and retrofitting older school
buses with cleaner alternatives
Page La~
http://www.ucsusa..org/clean_vehicles/big_rig_cleanup/?print=t 4/25/2006